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Journal article

Biocatalysts for selective introduction of oxygen

By Leak, D. J.; Sheldon, R. A.; Woodley, John1,2; Adlercreutz, P.

From

Center for BioProcess Engineering, Department of Chemical and Biochemical Engineering, Technical University of Denmark1

Department of Chemical and Biochemical Engineering, Technical University of Denmark2

Three types of oxygenase biocatalysts are treated in detail in this review: the non-haem iron alkene mono-oxygenases, the haem and vanadium haloperoxidases, and flavin-based Baeyer-Villiger mono-oxygenases. Other oxygenases are briefly included for comparison. Characteristics of the biocatalysts are presented, and the scope and limitations concerning their applicability for the selective introduction of oxygen are discussed.

Key issues include catalytic activity, productivity, cloning and expression, as well as process engineering aspects. Various bottlenecks are identified for the different biocatalysts and measures to increase the number of oxygenase reactions in practical use are discussed.

Language: English
Year: 2009
Pages: 1-26
ISSN: 10292446 and 10242422
Types: Journal article
DOI: 10.1080/10242420802393519
ORCIDs: Woodley, John
Keywords

Mono-oxygenase chloroperoxidase oxygenation peroxidase

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