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Journal article · Book chapter

Catalytic SILP materials

From

Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark1

Department of Chemistry, Technical University of Denmark2

The principle of catalytic SILP materials involves surface modification of a porous solid materialby an ionic liquid coating. Ionic liquids are salts with melting points below 100°C, generally characterizedby extremely low volatilities. In the examples described in this paper, the ionic liquid coating containsa homogeneously dissolved Rh-complex and constitutes a uniform, thin film, which itself displaysthe catalytic reactivity in the system.

Continuous fixed-bed reactor technology has been applied successfullyto demonstrate the feasibility of catalytic SILP materials for propene hydroformylation and methanol carbonylation.

Language: English
Publisher: Springer Berlin Heidelberg
Year: 2008
Pages: 149-162
Series: Topics in Organometallic Chemistry
ISBN: 3540710744 , 3540710760 , 9783540710745 and 9783540710769
ISSN: 16168534 and 14366002
Types: Journal article and Book chapter
DOI: 10.1007/3418_042
ORCIDs: Riisager, Anders and Fehrmann, Rasmus

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