Journal article
Octarubidium di-mu-sulfato-kappa O-4:O '-bis[cis-dioxido-cis-disulfatotungstate(VI)]
The title compound, Rb8[W2O4(SO4)6], was precipitated from a melt of tungsten(VI) oxide and rubidium sulfate in rubidium disulfate. The unit cell contains two discrete [{WVIO2(SO4)2}2([mu]-SO4)2]8- units connected by Rb-O coordination. The W atom is octahedrally surrounded by two oxide ligands, two terminal sulfate ligands and two bridging sulfate groups.
One Rb atom is coordinated by eight O atoms, whereas the three other Rb atoms are coordinated by nine O atoms from sulfate and oxide groups, leading to distorted [RbOx] polyhedra.
Language: | English |
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Publisher: | International Union of Crystallography |
Year: | 2009 |
Pages: | i88-i88 |
ISSN: | 16005368 |
Types: | Journal article |
DOI: | 10.1107/S1600536809046431 |
ORCIDs: | Ståhl, Kenny and Berg, Rolf W. |