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Journal article

Directed magnetic field induced assembly of high magnetic moment cobalt nanowires

From

Ceramic processing, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

Risø National Laboratory for Sustainable Energy, Technical University of Denmark3

Nanyang Technological University4

A directed magnetic field induced assembly technique was employed to align two phase (h.c.p. + f.c.c.) cobalt nanoparticles in a mechanically robust long wire morphology. Co nanoparticles with an average size of 4.3 nm and saturation magnetization comparable to bulk cobalt were synthesized by borohydride reduction followed by size selection and magnetic field induced assembly.

The coercivity of these nanowires was higher than their nanoparticle counterpart due to shape anisotropy. The experimental coercivity values of the nanowires were lower than the predictions of the coherent rotation, fanning and curling models of coercivity due to the preponderance of superparamagnetic particles with zero coercivity.

Language: English
Publisher: Springer-Verlag
Year: 2010
Pages: 821-830
Journal subtitle: Materials Science and Processing
ISSN: 14320630 and 09478396
Types: Journal article
DOI: 10.1007/s00339-009-5537-z

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