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Journal article

Oxygen release and exchange in niobium oxide MEHPPV hybrid solar cells

From

Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Solar Energy Programme, Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

We demonstrate that niobium oxide exchanges oxygen with the atmosphere when illuminated by simulated sunlight. The oxygen exchange was found to take place for pristine niobium oxide films when illuminated in an oxygen atmosphere and when illuminated in an operational hybrid solar cell. The oxygen exchange was demonstrated using O-18(2)-isotopic labeling in combination with time-of-flight secondary ion mass spectrometry (TOF-SIMS) imaging analysis of devices and oxide substrates.

TOF-SIMS depth profiling confirmed O-18 incorporation throughout the device in hybrid solar cells. The results are discussed in the context of hybrid solar cell stability and illuminate one of the degradation paths.

Language: English
Year: 2006
Pages: 5684-5690
ISSN: 15205002 and 08974756
Types: Journal article
DOI: 10.1021/cm061429d
ORCIDs: Norrman, K. , Andreasen, J.W. and Krebs, Frederik C

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