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Journal article

Novofumigatonin, a New Orthoester Meroterpenoid from Aspergillus novofumigatus

By Rank, Christian1,2; Phipps, Richard Kerry1,2; Harris, Pernille3,4; Fristrup, Peter4; Larsen, Thomas Ostenfeld1,2; Gotfredsen, Charlotte Held4,5

From

Center for Microbial Biotechnology, Department of Systems Biology, Technical University of Denmark1

Department of Systems Biology, Technical University of Denmark2

X-ray Crystallography, Department of Chemistry, Technical University of Denmark3

Department of Chemistry, Technical University of Denmark4

Organic Chemistry, Department of Chemistry, Technical University of Denmark5

Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark6

Novofumigatonin (1), a new metabolite, has been isolated from Aspergillus novofumigatus. The structure and relative stereochemistry were determined from HR ESI MS, one- and two-dimensional NMR, and single-crystal X-ray analysis. The absolute configuration was assigned using vibrational circular dichroism in combination with density functional calculations.

Language: English
Year: 2008
Pages: 401-404
ISSN: 15237052 and 15237060
Types: Journal article
DOI: 10.1021/ol7026834
ORCIDs: Harris, Pernille , Fristrup, Peter , Larsen, Thomas Ostenfeld and Gotfredsen, Charlotte Held
Keywords

Aspergillus Circular Dichroism Crystallography, X-Ray Molecular Conformation Molecular Structure Terpenes fumigatonin novofumigatonin

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