Journal article
High temperature electrolyte supported Ni-GDC/YSZ/LSM SOFC operation on two-stage Viking gasifier product gas
This paper presents the results from a 150 h test of a commercial high temperature single planar solid oxide fuel cell (SOFC) operating on wood gas from the Viking two-stage fixed-bed downdraft gasifier, which produces an almost tar-free gas, that was further cleaned for particulates, sulphur and tar traces.
The chosen SOFC was electrolyte supported with a nickel/gadolinium-doped cerium oxide (Ni-GDC) anode, known for its carbon deposition resistance. Through humidification the steam to carbon ratio (S/C) was adjusted to 0.5, which results in a thermodynamically carbon free condition at the SOFC operating temperature T = 850 degrees C.
The cell operated with a fuel utilisation factor (U-f) around 30% and a current density of 260 mA cm(-2) resulting in an average power density of 207 mW cm(-2). Throughout the duration of the test, only a minor cell overpotential increase of 10 mV was observed. Nevertheless, the V-j (voltage-current density) curves on H-2/N-2 before and after the wood gas test proved identical.
Extensive SEM/EDS examination of the cell's anode showed that there was neither carbon deposition nor significant shifts in the anode microstructure or contamination when compared to an identical cell tested on H-2/N-2 only.
Language: | English |
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Year: | 2007 |
Pages: | 357-366 |
ISSN: | 18732755 and 03787753 |
Types: | Journal article |
DOI: | 10.1016/j.jpowsour.2007.04.073 |
ORCIDs: | Ahrenfeldt, Jesper and Henriksen, Ulrik Birk |