Journal article
Application of sPC-SAFT and group contribution sPC-SAFT to polymer systems-Capabilities and limitations
Department of Chemical and Biochemical Engineering, Technical University of Denmark1
Center for Phase Equilibria and Separation Processes, Department of Chemical and Biochemical Engineering, Technical University of Denmark2
Center for Energy Resources Engineering, Centers, Technical University of Denmark3
A group contribution (GC) version of the simplified Perturbed-Chain Statistical Associating Fluid Theory (sPC-SAFT) Equation of State is proposed in a previous work [A. Tihic, G.M. Kontogeorgis, N. von Solms, M.L. Michelsen, L Constantinou, Ind. Eng. Chem. Res. 47 (2008) 5092-5101]. The reported predictive capability of the model demonstrates satisfactory description of the fluid behaviour of several polymer systems, including both vapour-liquid equilibria and liquid-liquid equilibria.
This work continues the systematic study on phase behaviour of polymer systems with the two versions of the sPC-SAFT model, with and without GC. The reported results contribute to a better understanding of the applicability of the sPC-SAFT model to binary polymer mixtures, and identify both models as good predictive tools for several industrial applications.
Limitations are also identified and discussed.
| Language: | English |
|---|---|
| Year: | 2009 |
| Pages: | 70-77 |
| ISSN: | 03783812 and 18790224 |
| Types: | Journal article |
| DOI: | 10.1016/j.fluid.2009.04.002 |
| ORCIDs: | von Solms, Nicolas and Kontogeorgis, Georgios |
