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Journal article

Comment on "Active sites for CO2 hydrogenation to methanol on Cu/ZnO catalysts"

In Science 2017, Volume 357, Issue 6354, pp. eaan8074-eaan8074
From

University of Tsukuba1

National Institute of Advanced Industrial Science and Technology2

Haldor Topsoe AS3

Department of Physics, Technical University of Denmark4

Surface Physics and Catalysis, Department of Physics, Technical University of Denmark5

Kattel et al (Reports, 24 March 2017, p. 1296) report that a zinc on copper (Zn/Cu) surface undergoes oxidation to zinc oxide/copper (ZnO/Cu) during carbon dioxide (CO2) hydrogenation to methanol and conclude that the Cu-ZnO interface is the active site for methanol synthesis. Similar experiments conducted two decades ago by Fujitani and Nakamura et al demonstrated that Zn is attached to formate rather than being fully oxidized.

Language: English
Publisher: American Association for the Advancement of Science
Year: 2017
Pages: eaan8074-eaan8074
ISSN: 10959203 and 00368075
Types: Journal article
DOI: 10.1126/science.aan8074
ORCIDs: 0000-0002-2837-0535 , 0000-0002-1225-3246 , 0000-0001-5314-3214 , Chorkendorff, Ib and 0000-0002-1035-668X

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