Journal article
Transformation and migration in secondary zinc-air batteries studied by in situ synchrotron X-ray diffraction and X-ray tomography
Electrochemical Materials, Department of Energy Conversion and Storage, Technical University of Denmark1
Department of Energy Conversion and Storage, Technical University of Denmark2
University of Copenhagen3
Imaging and Structural Analysis, Department of Energy Conversion and Storage, Technical University of Denmark4
There are numerous challenges associated with developing secondary Zn-air batteries regarding e.g. power density and cycle life. Some of the challenges are related to morphological changes in the anode during cycling due to combined electrochemical and chemical processes involved in the reversible Zn – ZnO transformation.
We present a unique in situ synchrotron X-ray diffraction study, where a combination of time and spatial resolution allows information about transformation and transport in a Zn/ZnO anode during discharge/charge operation. By tracking Zn and ZnO reflections during cycling of two Zn-air batteries we see that the conversion of these phases is accompanied by transport into the anode and the anode configuration does not return to its initial state after recharge due to ZnO migration to other parts of the battery.
During charge Zn metal is deposited as microcrystalline material, changing the morphology and phase distribution in the anode. The XRD results were supported by qualitative in situ X-ray computed tomography that confirms depletion of ZnO and non-homogeneous distribution of Zn.
Language: | English |
---|---|
Year: | 2019 |
Pages: | 6459-6466 |
ISSN: | 20507496 and 20507488 |
Types: | Journal article |
DOI: | 10.1039/C8TA11554K |
ORCIDs: | Simonsen, Søren Bredmose , Norby, Poul , 0000-0003-1423-4724 and 0000-0001-6252-4131 |