Journal article
A multiple length scale description of the mechanism of elastomer stretching
Oak Ridge National Laboratory1
Department of Chemical and Biochemical Engineering, Technical University of Denmark2
The Danish Polymer Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark3
University of New South Wales4
European Synchrotron Radiation Facility5
Roskilde University6
Department of Physics, Technical University of Denmark7
Neutrons and X-rays for Materials Physics, Department of Physics, Technical University of Denmark8
Conventionally, the stretching of rubber is modeled exclusively by rotations of segments of the embedded polymer chains; i.e. changes in entropy. However models have not been tested on all relevant length scales due to a lack of appropriate probes. Here we present a universal X-ray based method for providing data on the structure of rubbers in the 2-50 angstrom range.
First results relate to the elongation of a silicone rubber. We identify several non-entropic contributions to the free energy and describe the associated structural changes. By far the largest contribution comes from structural changes within the individual monomers, but among the contributions is also an elastic strain, acting between chains, which is 3-4 orders of magnitude smaller than the macroscopic strain, and of the opposite sign, i.e. extension of polymer chains in the direction perpendicular to the stretch.
This may be due to trapped entanglements relaxing to positions close to the covalent crosslinks.
Language: | English |
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Year: | 2016 |
Pages: | 95910-95919 |
ISSN: | 20462069 |
Types: | Journal article |
DOI: | 10.1039/c6ra22802j |
ORCIDs: | Skov, Anne Ladegaard , Oddershede, Jette , Poulsen, Henning Friis and 0000-0002-4018-6431 |