Journal article
An Equation-of-State Compositional In-Situ Combustion Model: A Study of Phase Behavior Sensitivity
Department of Chemical and Biochemical Engineering, Technical University of Denmark1
Department of Informatics and Mathematical Modeling, Technical University of Denmark2
Center for Phase Equilibria and Separation Processes, Department of Chemical and Biochemical Engineering, Technical University of Denmark3
In order to facilitate the study of reactive-compositional porous media processes we develop a virtual kinetic cell (single-cell model) as well as a virtual combustion tube (one-dimensional model). Both models are fully compositional based on an equation of state. We employ the models to study phase behavior sensitivity for in situ combustion, a thermal oil recovery process.
For the one-dimensional model we first study the sensitivity to numerical discretization errors and provide grid density guidelines for proper resolution of in situ combustion behavior. A critical condition for success of in situ combustion processes is the formation and sustained propagation of a high-temperature combustion front.
Using the models developed, we study the impact of phase behavior on ignition/extinction dynamics as a function of the operating conditions. We show that when operating close to ignition/extinction branches, a change of phase behavior model will shift the system from a state of ignition to a state of extinction or vice versa.
For both the rigorous equation of state based and a simplified, but commonly used, K-value-based phase behavior description we identify areas of operating conditions which lead to ignition. For a particular oil we show that the simplified approach overestimates the required air injection rate for sustained front propagation by 17% compared to the equation of state-based approach.
Language: | English |
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Publisher: | Springer Netherlands |
Year: | 2009 |
Pages: | 219-246 |
ISSN: | 15731634 and 01693913 |
Types: | Journal article |
DOI: | 10.1007/s11242-008-9244-6 |
ORCIDs: | Stenby, Erling Halfdan |