Journal article
Asymmetric Total Syntheses of (-)-α-Lycorane, (-)-Zephyranthine and Formal Synthesis of (+)-Clivonine
We report the successful achievement of an asymmetric route to (-)-α-lycorane and (-)-zephyranthine as well as a formal total synthesis of (+)-clivonine. A pivotal intermediate, which serves as a potent precursor for the divergent syntheses of these natural products, was accessed by a diastereoselective Pd-catalyzed cinnamylation of an N-tert-butanesulfinyl imine.
Language: | English |
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Year: | 2017 |
Pages: | 1309-1313 |
ISSN: | 1861471x and 18614728 |
Types: | Journal article |
DOI: | 10.1002/asia.201700555 |
ORCIDs: | Kramer, Søren and 0000-0003-0432-7935 |