Journal article
Highly Selective Continuous Gas-Phase Methoxycarbonylation of Ethylene with Supported Ionic Liquid Phase (SILP) Catalysts
Supported ionic liquid phase (SILP) technology was applied for the first time to the Pd-catalyzed continuous, gas-phase methoxycarbonylation of ethylene to selectively produce methyl propanoate (MP) in high yields. The influence of catalyst and reaction parameters such as, for example, ionic liquid loading, metal concentration, and ligand loadings was studied, and in particular the SILP catalyst activity and stability was found to be strongly dependent on the ligand to metal ratio.
Language: | English |
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Year: | 2017 |
Pages: | 1824-1829 |
ISSN: | 18673899 and 18673880 |
Types: | Journal article |
DOI: | 10.1002/cctc.201601428 |
ORCIDs: | Garcia Suárez, Eduardo José , Fehrmann, Rasmus and Riisager, Anders |