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Journal article

Corrosion Study of Cr-Oxide Ceramics Using Rotating Ring Disk Electrode

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Electrochemical Materials, Department of Energy Conversion and Storage, Technical University of Denmark2

Proton Exchange Membrane Electrolysis demands new resistant and cheap materials for the anode components, and Cr-based spinels are acid stable ceramics, which may meet the requirements of such application to some extent. This work reports the electrochemical behavior of spinel-structured MnCu0.25Cr1.75O4 and NiCr2O4 up to 2.0 V in order to determine the stability/dissolution of such materials when exposed to anodic potential.

The ceramic/graphite composite was deposited on a rotating ring disk electrode and scanned while the ring electrode was held at 0.5 V vs SHE. The dissolution of Cr species was observed to happen as the oxidation proceeded by collecting the dissolved products at the ring electrode. HCrO4− and MnO4− were identified as dissolved products.

Analysis of post-test solutions, revealed the difference between chemical and electrochemical corrosion of the materials.

Language: English
Publisher: The Electrochemical Society
Year: 2019
Pages: C3159-C3169
ISSN: 19457111 and 00134651
Types: Journal article
DOI: 10.1149/2.0191911jes
ORCIDs: Kammer Hansen, Kent , Mogensen, Mogens Bjerg and 0000-0002-5525-9779

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