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Journal article · Conference paper

Environmental TEM investigation of the reduction of α-Fe2O3 nanorods under H2 atmosphere

From

University of Nottingham1

University of Exeter2

Center for Electron Nanoscopy, Technical University of Denmark3

The thermal reduction of hydrothermally synthesised α-Fe2O3 nanorods (NRs) to Fe3O4 NRs under hydrogen is investigated. Complete reduction of α-Fe2O3 NRs to Fe3O4 NRs was achieved during in situ XRD under 1 bar H2 atmosphere at 360°C. Complementary environmental transmission electron microscope investigation at high resolution, during in situ heating under an H2 pressure of 5 mbar at 500°C, provided evidence for the very first stages of transformation, supporting a model for the migration of oxygen along favoured α-Fe2O3 lattice planes during the templated thermal reduction of α-Fe2O3 NRs to Fe3O4 NRs.

Language: English
Publisher: IOP Publishing
Year: 2012
Pages: 012049 (4pp)
Proceedings: Electron Microscopy and Analysis Group Conference (EMAG 2011)
ISSN: 17426588 and 17426596
Types: Journal article and Conference paper
DOI: 10.1088/1742-6596/371/1/012049
ORCIDs: Hansen, Thomas Willum

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