Journal article
Ion-Exchange-Induced Selective Etching for the Synthesis of Amino-Functionalized Hollow Mesoporous Silica for Elevated-High-Temperature Fuel Cells
As differentiated from conventional synthetic processes, amino-functionalized hollow mesoporous silica (NH2–HMS) has been synthesized using a new and facile strategy of ion-exchange-induced selective etching of amino-functionalized mesoporous silica (NH2-meso-silica) by an alkaline solution. Nuclear magnetic resonance (NMR) spectroscopy and in situ time-resolved small-angle X-ray scattering (SAXS) reveal that ion-exchange-induced selective etching arises from the gradient distribution of OH– in the NH2-meso-silica nanospheres.
Moreover, the ion-exchange-induced selective etching mechanism is verified through a successful synthesis of hollow mesoporous silica. After infiltration with phosphotungstic acid (PWA), PWA–NH2–HMS nanoparticles are dispersed in the poly(ether sulfone)–polyvinylpyrrolidone (PES–PVP) matrix, forming a hybrid PWA–NH2–HMS/PES–PVP nanocomposite membrane.
The resultant nanocomposite membrane with an optimum loading of 10 wt % of PWA–NH2–HMS showed an enhanced proton conductivity of 0.175 S cm–1 and peak power density of 420 mW cm–2 at 180 °C under anhydrous conditions. Excellent durability of the hybrid composite membrane fuel cell has been demonstrated at 200 °C.
The results of this study demonstrated the potential of the facile synthetic strategy in the fabrication of NH2–HMS with controlled mesoporous structure for application in nanocomposite membranes as a technology platform for elevated-temperature proton exchange membrane fuel cells.
Language: | English |
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Publisher: | American Chemical Society (ACS) |
Year: | 2017 |
Pages: | 31922-31930 |
ISSN: | 19448252 and 19448244 |
Types: | Journal article |
DOI: | 10.1021/acsami.7b09591 |
ORCIDs: | 0000-0002-5114-0404 , 0000-0002-1357-3727 , 0000-0002-7042-2976 , Aili, David and Li, Qingfeng |