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Journal article

Cobalt release from inexpensive jewellery: has the use of cobalt replaced nickel following regulatory intervention?

From

Copenhagen University Hospital Herlev and Gentofte1

Materials and Surface Engineering, Department of Mechanical Engineering, Technical University of Denmark2

Department of Mechanical Engineering, Technical University of Denmark3

Karolinska Institutet4

Objectives: The aim was to study 354 consumer items using the cobalt spot test. Cobalt release was assessed to obtain a risk estimate of cobalt allergy and dermatitis in consumers who would wear the jewellery. Methods: The cobalt spot test was used to assess cobalt release from all items. Microstructural characterization was made using scanning electron microscope (SEM) and energy-dispersive spectroscopy (EDS).

Results: Cobalt release was found in 4 (1.1%) of 354 items. All these had a dark appearance. SEM/EDS was performed on the four dark appearing items which showed tin-cobalt plating on these. Conclusions: This study showed that only a minority of inexpensive jewellery purchased in Denmark released cobalt when analysed with the cobalt spot test.

As fashion trends fluctuate and we found cobalt release from dark appearing jewellery, cobalt release from consumer items should be monitored in the future. Industries may not be fully aware of the potential cobalt allergy problem.

Language: English
Year: 2010
Pages: 70-76
ISSN: 16000536 , 01051873 and 13966669
Types: Journal article
DOI: 10.1111/j.1600-0536.2010.01752.x
ORCIDs: Jellesen, Morten Stendahl

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