Journal article
Thermodynamic assessment of the CoOx-CrO1.5 system
Electroceramics, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1
Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark2
Risø National Laboratory for Sustainable Energy, Technical University of Denmark3
By application of the CALPHAD method, a consistent set of thermodynamic model parameters is optimized for the oxide phases in the Co–Cr–O system. Cobalt chromium spinel is described as a normal spinel at room temperature and with cation redistribution at high temperature. All the solid oxide solution phases are described using the compound energy model, and the liquid phase is described using the two-sublattice model for ionic liquids.
Calculated phase diagrams are presented, and values for the thermodynamic properties are compared with experimental data.
Language: | English |
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Year: | 2009 |
Pages: | 427-434 |
ISSN: | 18734669 and 09258388 |
Types: | Journal article |
DOI: | 10.1016/j.jallcom.2009.05.135 |
ORCIDs: | Chen, Ming |