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Journal article

Subsolidus Phase Relations of the CaO-WO₃-CuO System at 800 °C in Air

In Journal of Phase Equilibria and Diffusion — 2012, Volume 33, Issue 1, pp. 46-50

From

Department of Energy Conversion and Storage, Technical University of Denmark¹

Electrofunctional materials, Department of Energy Conversion and Storage, Technical University of Denmark²

Abstract

The subsolidus phase relations of the CaO-WO3-CuO system were investigated in air. The samples were equilibrated at 800 degrees C. Under these conditions, five binary oxide phases are stable: Ca2CuO3, Cu3WO6, CuWO4, CaWO4 and Ca3WO6. The pseudo-ternary section is characterised by 6 three-phase regions.

No Ca equivalents to the Sr2CuWO6, Ba2CuWO6 or Sr8CuW3O18 phases were formed.

Language:	English
Publisher:	Springer US
Year:	2012
Pages:	46-50
ISSN:	18637345 and 15477037
Types:	Journal article
DOI:	10.1007/s11669-012-9990-6
ORCIDs:	Grivel, J. -C.

Keywords

CAO-CUO Chemistry Crystal structure Equilibria High-pressure Materials Metallurgy O system Oxygen Tungstates

Other keywords

CaO-WO3-CuO Ceramics, Glass, Composites, Natural Methods Crystallography Engineering Thermodynamics, Heat and Mass Transfer Materials Science, general Metallic Materials Physics Thermodynamics X-ray diffraction phase equilibria

Subsolidus Phase Relations of the CaO-WO₃-CuO System at 800 °C in Air

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Subsolidus Phase Relations of the CaO-WO₃-CuO System at 800 °C in Air