Journal article
Conductivity, transport number measurements and hydration thermodynamics of BaCe0.2Zr0.7Y(0.1 − ξ)NiξO(3 − δ)
Electroceramics, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1
Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark2
Risø National Laboratory for Sustainable Energy, Technical University of Denmark3
Microstructures and Interfaces, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark4
University of Oslo5
BaCe0.2Zr0.7Y(0.1 − ξ)NiξO(3 − δ) compounds with ξ = 0.01 and 0.02 have been synthesized by solid state reaction at 1400 °C and sintered at 1450 °C. TEM analyses were performed and showed a segregation of nickel at the grain boundaries for ξ = 0.02. This apparent solubility limit of Ni in the B-site of the perovskite is in agreement with similar data obtained earlier for the two compositions.
The first aim of this work was to evaluate the conductivity of BaCe0.2Zr0.7Y(0.1 − ξ)NiξO(3 − δ) at temperature between 500 and 900 °C, using impedance spectroscopy at different oxygen partial pressures and water vapor pressures, as well as the emf technique. The compounds exhibit p-type conduction in oxidizing atmosphere, and ionic conduction elsewhere.
The oxide ion contribution of the conductivity is negligible only for temperatures below 600 °C. The determination of hydration enthalpies, our second goal, was achieved by modelling of the conductivity data and by thermogravimetric measurements (TG-DSC).
| Language: | English |
|---|---|
| Year: | 2011 |
| Pages: | 11-17 |
| ISSN: | 18727689 and 01672738 |
| Types: | Journal article |
| DOI: | 10.1016/j.ssi.2010.12.012 |
| ORCIDs: | Bonanos, Nikolaos |
