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Journal article

A method to separate process contributions in impedance spectra by variation of test conditions

From

Electrochemistry, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark1

Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark2

Risø National Laboratory for Sustainable Energy, Technical University of Denmark3

Electroceramics, Fuel Cells and Solid State Chemistry Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark4

Physical Chemistry, Department of Chemistry, Technical University of Denmark5

Department of Chemistry, Technical University of Denmark6

Many processes contribute to the overall impedance of an electrochemical cell, and these may be difficult to separate in the impedance spectrum. Here, we present an investigation of a solid oxide fuel cell based on differences in impedance spectra due to a change of operating parameters and present the result as the derivative of the impedance with respect to ln(f).

The method is used to separate the anode and cathode contributions and to identify various types of processes.

Language: English
Publisher: The Electrochemical Society
Year: 2007
Pages: B1325
ISSN: 19457111 and 00134651
Types: Journal article
DOI: 10.1149/1.2790791
ORCIDs: Hauch, Anne , Hendriksen, Peter Vang , Mogensen, Mogens Bjerg and Bonanos, Nikolaos

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