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Journal article

Formation of a metallic glass by thermal decomposition of Fe(CO)5

By Wonterghem, Jacques van1; Mørup, Steen2,3; Charles, Stuart W.; Wells, Stephen; Villadsen, J.4

From

Technical University of Denmark1

Quantum Physics and Information Technology, Department of Physics, Technical University of Denmark2

Department of Physics, Technical University of Denmark3

Haldor Topsoe AS4

Iron pentacarbonyl has been thermally decomposed in an organic liquid. Mössbauer spectroscopy and x-ray diffraction studies show that the sample contains small particles of a metallic glass. Annealing of the particles at 523 K results in crystallization of the particles into a mixture of α-Fe and χ-Fe5C2.

The mechanism of glass formation is discussed.

Language: English
Year: 1985
Pages: 410-413
ISSN: 10797114 and 00319007
Types: Journal article
DOI: 10.1103/PhysRevLett.55.410

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