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Journal article

Communication—Perovskite Electrochemical System for Highly Selective NOx Reduction of Diesel Engine Exhaust

From

Shenzhen University1

Department of Energy Conversion and Storage, Technical University of Denmark2

Proton conductors, Department of Energy Conversion and Storage, Technical University of Denmark3

Southern University of Science and Technology4

Electrochemical Materials and Interfaces, Department of Energy Conversion and Storage, Technical University of Denmark5

A perovskite electrochemical system was developed for selective NOx reduction of diesel engine exhaust. The system was composed of a La0.9Sr0.1CoO3±δ oxidation catalyst and a (La0.85Sr0.15)0.95MnO3±δ/Ce0.9Gd0.1O1.95 electrochemical cell with BaO nanopariticles. A selectivity of 25–35% was achieved with a NOx conversion of 65–75% in 1000 ppm NO with 8% O2 at 375°C.

The superior performance of the system was suggested to be ascribed to the promotion in NO2 formation substantially activating the NOx trapping and reduction processes on the electrode.

Language: English
Publisher: The Electrochemical Society
Year: 2018
Pages: H591-H593
ISSN: 19457111 and 00134651
Types: Journal article
DOI: 10.1149/2.0261810jes
ORCIDs: Zhang, Wenjing , Hansen, Kent Kammer and 0000-0002-0514-5642

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