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Journal article

Atomic resolution imaging of precipitate transformation from cubic TaN to tetragonal CrTaN

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Department of Mechanical Engineering, Technical University of Denmark1

Materials and Surface Engineering, Department of Mechanical Engineering, Technical University of Denmark2

In 9–12% Cr creep-resistant steels Cr(V,Nb,Ta)N Z-phase is known to replace metastable (V,Nb,Ta)N MN precipitates at high temperatures. The precipitation process of Z-phase does not follow the classical nucleation theory, where dissolving MN particles provide constituents for Z-phase nucleation in the matrix.

Using atomic resolution transmission electron microscopy, the current work demonstrates that metastable cubic TaN precipitates in a complex steel gradually transform compositionally and crystallographically into stable tetragonal CrTaN precipitates under the influence of Cr indiffusion from the steel matrix.

Language: English
Year: 2012
Pages: 261-264
ISSN: 18728456 and 13596462
Types: Journal article
DOI: 10.1016/j.scriptamat.2011.11.005
ORCIDs: Danielsen, Hilmar Kjartansson , Hald, John and Somers, Marcel A. J.

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