Journal article
Catalytic Tandem Reaction for the Production of Jet and Diesel Fuel Range Alkanes
Guizhou University1
East China University of Science and Technology2
Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark3
Organic Chemistry, Department of Chemistry, Technical University of Denmark4
Department of Chemistry, Technical University of Denmark5
Jet and diesel fuels are typically composed of C9-C14 and C12-C20 hydrocarbons, respectively, but the carbon-chain length of sugar-derived aldehydes and furanic compounds is no longer than C6. Here, a cascade catalytic process involving alkylation and hydrodeoxygenation (HDO) of 2-methylfuran (2-MF) with different aldehydes is conducted to directly produce long-chain alkanes with exclusive carbon number of C11-C17 in overall yields of 50-84%.
Preliminary investigations on the alkylation of 2-MF and formalin show that the relative density of Lewis and Brønsted acidic sites of zeolitic materials remarkably affect their catalytic activity and selectivity. Sn-beta(12.5) with pronounced Lewis acidity (including the acid density and strength) exhibits higher catalytic performance in the alkylation than other zeolites, producing long-chain oxygenates in 58-92% yields.
Even in aqueous solution, the Sn-beta(12.5) catalyst can be reused for at least six reaction cycles with almost constant reactivity. More importantly, the co-addition of Hf(OTf)4 with Pd/C greatly promotes C-O bond cleavage of the furan-ring during the HDO process under mild reaction conditions, producing long-chain alkanes in high yields of 84-94%.
Language: | English |
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Year: | 2018 |
Pages: | 1060-1066 |
ISSN: | 21944296 and 21944288 |
Types: | Journal article |
DOI: | 10.1002/ente.201700637 |
ORCIDs: | 0000-0002-3980-5020 and Riisager, Anders |