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Journal article

Protein repellent hydrophilic grafts prepared by surface-initiated atom transfer radical polymerization from polypropylene

By Fristrup, Charlotte Juel1; Jankova Atanasova, Katja1,2; Eskimergen, Rüya3; Bukrinsky, Jens T.3; Hvilsted, Søren1,2

From

Department of Chemical and Biochemical Engineering, Technical University of Denmark1

The Danish Polymer Centre, Department of Chemical and Biochemical Engineering, Technical University of Denmark2

Novo Nordisk Foundation3

Grafting of poly(ethylene glycol)methacrylate (PEGMA) and N,N-dimethylacrylamide (DMAAm) from UV-initiator modified polypropylene (PP) was performed by Surface-Initiated Atom Transfer Radical Polymerization (SI-ATRP). The modification and hydrophilization of the PP substrates were confirmed with Attenuated Total Reflectance (ATR) Fourier Transform Infrared (FTIR) spectroscopy and Water Contact Angle (WCA) measurements.

Confocal fluorescence microscopy of modified and unmodified substrates immersed in labelled insulin aspart showed superior repulsion of this protein for the poly(PEGMA) grafts, due to the achieved architecture.

Language: English
Year: 2012
Pages: 198-203
ISSN: 17599962 and 17599954
Types: Journal article
DOI: 10.1039/c1py00347j
ORCIDs: Jankova Atanasova, Katja

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