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Conference paper · Journal article

Improved oxidation resistance of ferritic steels with LSM coating for high temperature electrochemical applications

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Mixed Conductors, Department of Energy Conversion and Storage, Technical University of Denmark2

The effect of single layer La0.85Sr0.15MnO3−δ (LSM) coatings on high temperature oxidation behaviour of four commercial chromia-forming steels, Crofer 22 APU, Crofer 22 H, E-Brite and AL 29-4C, is studied. The samples were oxidized for 140–1000 h at 1123 K in flowing simulated ambient air (air + 1% H2O) and oxygen and corrosion kinetics monitored by mass increase of the materials over time.

The oxide scale microstructure and chemical composition are investigated by scanning electron microscopy/energy-dispersive spectroscopy. The kinetic data obey a parabolic rate law. The results show that the LSM coating acts as an oxygen transport barrier that can significantly reduce the corrosion rate.

Language: English
Year: 2012
Pages: 8087-8094
Proceedings: 7th Petite Workshop on the Defect Chemical Nature of Energy Materials
ISSN: 18793487 and 03603199
Types: Conference paper and Journal article
DOI: 10.1016/j.ijhydene.2011.11.138
ORCIDs: Chen, Ming and Hendriksen, Peter Vang

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