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Journal article

Tungsten carbide promoted Pd and Pd–Co electrocatalysts for formic acid electrooxidation

By Yin, Min; Li, Qingfeng1,2; Jensen, Jens Oluf1,2; Huang, Yunjie1,2; Cleemann, Lars Nilausen1,2; Bjerrum, Niels1,2; Xing, Wei3

From

Department of Energy Conversion and Storage, Technical University of Denmark1

Proton conductors, Department of Energy Conversion and Storage, Technical University of Denmark2

Chinese Academy of Sciences3

Tungsten carbide (WC) promoted palladium (Pd) and palladium–cobalt (Pd–Co) nanocatalysts are prepared and characterized for formic acid electrooxidation. The WC as the dopant to carbon supports is found to enhance the CO tolerance and promote the activity of the Pd-based catalysts for formic acid oxidation.

Alloying of Pd with Co further improves the electrocatalytic activity and stability of the WC supported catalysts, attributable to a synergistic effect of the carbide support and PdCo alloy nanoparticles.

Language: English
Year: 2012
Pages: 106-111
ISSN: 18732755 and 03787753
Types: Journal article
DOI: 10.1016/j.jpowsour.2012.07.032
ORCIDs: Li, Qingfeng , Jensen, Jens Oluf , Cleemann, Lars Nilausen and Bjerrum, Niels
Keywords

Catalysts Electrooxidation Formic acid Palladium-cobalt Tungsten carbide

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