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Conference paper

Ionic motion in PEDOT and PPy conducting polymer bilayers

In Solid State Ionics: Advanced Materials for Emerging Technologies — 2006, pp. 671-678
From

University of Peradeniya1

Department of Chemistry, Technical University of Denmark2

Conducting polymer bilayers with poly(3,4-ethylenedioxythiophene) (PEDOT) and polypyrrole (PPy), each containing dodecyl benzenesulfonate (DBS) as immobile dopant species, were synthesized galvanostatically. The electrochemical behaviour of the bilayers was investigated using cyclic voltammetry, optical absorption spectroscopy and electrochemical quartz crystal microbalance (EQCM) techniques.

Two important conclusions of relevance for actuator performance were reached: It is possible to make a bilayer film that does not delaminate – the two polymers are compatible; and both polymers are active in the redox process as ions are able to move through the PEDOT layer and penetrate into PPy.

Language: English
Publisher: World Scientific
Year: 2006
Pages: 671-678
Proceedings: 10th Asian Conference on Solid State Ionics
ISBN: 128137332x , 9812568778 , 981277310x , 9781281373328 , 9789812568779 and 9789812773104
Types: Conference paper

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