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Interpreted as:

title:(Some AND Chemical AND Kinetics AND Issues AND in AND Reburning\: AND The AND Branching AND Fraction AND of AND the AND HCCO+NO AND Reaction)

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1 Book chapter

Some Chemical Kinetics Issues in Reburning: The Branching Fraction of the HCCO+NO Reaction

Miller, James A.; Durant, J.L.; Glarborg, Peter

Vol 27 — 1998, pp. 235-243

Year: 1998

Language: English

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2 Journal article

Some chemical kinetics issues in reburning: The branching fraction of the HCCO+NO reaction

We have determined theoretically some critical kinetic parameters in the mechanism of NOx reburning under flow-reactor conditions. Specifically, using a variety of electronic-structure methods to investigate the potential energy surfaces and the maximum free-energy method of Quack and Troe to determine the resulting rate coefficients, we have deduced the values of k2 and k3 for the reactions HCNO+O a3HCO+NO (R2) and HCNO+OH a3HCOH+NO (R3) to be k2≈7×1013 cm3/mole s and k3≈2×1013 cm3/mole s independent of temperature for 300 K

Year: 1998

Language: English

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